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I seen the film, it kills humans in seconds. But I'm pointing out how common it is in fiction to assume that's how poisons work.

That's more a bad show for the cockpits of those vehicles, than an impressive showing for the arrows. No way no how non-metal arrows are going to punch through military-grade armor glass, especially !FUTURE! armored glass from a nation of FTL-capable humans. I bet the physical impact of such...

Going to give it to the Catachan dudes here. Their planet has small frogs which explode like poison-nukes, and feral Tyranid monsters. I'm not even convinced the Navi arrows can penetrate flak armor, let alone carapace and canonically stronger stuff like non-Spacemarine power armor suits exist...