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So probably not an in demand trade good. The Indians aren't passing around random crap on speculation so that tin making it to the Carolinas is very unlikely.

Copper doesn't do much without tin or arsenic. There's a reason the chalcolithic is considered part of the stone age: copper and gold look pretty, but it aren't hard enough to make good tools so the work is still done with stone. I think you get some stuff like needles that don't need hardness...